Wish it were that easy, but I don't think it is.
The 100 octane rating for the AvGas is a Motor octane number, while the 92 pump gas octane number is likely a Research + Motor / 2 (R+M/2) octane number, which would result in less than 92 Motor octane. So with this much in mind, one cannot make a 50/50 blend of the two fuels (with different type octane ratings) and thereby achieve a "mid-way average" octane rated fuel.
To further compound the issue: I once read a laboratory study that took place back when we all used to be able to purchase both leaded and unleaded pump gas at the pump. It was found that if the unleaded fuel already had a 92 octane rating without any lead in it, adding a splash of leaded regular would kick up the octane rating of the fuel more than what a simple math calculaton would suggest, meaning that there is chemistry at work here as well. I'm afraid I don't remember the leaded/non-leaded fuel proportions in the report, but I recall it was very little, like a few of gallons leaded regular added to a tankful of unleaded. I don't know that the AvGas will work this way exactly, but I do know that the last leaded pump gas had 1/10 gram/gallon in it and that AvGas has twenty times this amount (2 gr/gal).
LO
Oh shit, did someone mention Chemistry?
The only thing I know about that relates to the various studies and experiments I have done with ethyl alcohol....... :crossx: